Synthesis and Characterization of New Metal- Organic Framework Derived from 6- (Methoxycarbonyl) Pyridine-2-Carboxylic Acid as Application for Hydrogen Storage Materials

Maisara Abdul Kadir; Nafisah Mansor; Wan M. Khairul; Mohd Sukeri Mohd Yusof; Mohammad Ismail

Synthesis and Characterization of New Metal- Organic Framework Derived from 6- (Methoxycarbonyl) Pyridine-2-Carboxylic Acid as Application for Hydrogen Storage Materials

Files

123-Synthesis and Characterization of New Metal-Organic Framework Derived from 6-(Methoxycarbonyl) Pyridine-2-Carboxylic Acid as Application for Hydrogen Storage Materials.pdf (690.02 KB)

Date

2016

Authors

Maisara Abdul Kadir

Nafisah Mansor

Wan M. Khairul

Mohd Sukeri Mohd Yusof

Mohammad Ismail

Publisher

International Journal of Applied Chemistry

Abstract

In this study, a new organic linker namely 6-(pyrimidin-2-ylcarbamoyl)-pyridine-2- carboxylic acid methyl ester (L1) has been successfully synthesized. Along with this discovery, two metal-organic frameworks (MOFs) which derived from L1 and 6- (methoxycarbonyl)pyridine-2-carboxylic acid (L), have also been synthesized and characterized by using combination of spectroscopic techniques such as Infrared (IR), Nuclear Magnetic Resonances (NMR), Thermal Gravimetric Analysis (TGA) and Xray crystallography.

Keywords

Hydrogen storage, 6-(methoxycarbonyl) pyridine-2-carboxylic acid, hydrogen uptake, tridentate ligand, metal-organic framework

Citation

Vol. 12, No. 3

URI

http://hdl.handle.net/123456789/5497

Full item page