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dc.contributor.authorWan Mohd Khairul Wan Mohamed Zin-
dc.date.accessioned2011-05-31T03:58:52Z-
dc.date.available2011-05-31T03:58:52Z-
dc.date.issued2007-09-
dc.identifier.urihttp://hdl.handle.net/123456789/720-
dc.description.abstractThis thesis describes the synthesis and analysis of organometallic complexes that feature oligo-phenylene ethynylene based ligands. Chapter 1 introduces the general topic of molecular electronics and provides a general overview of the interest in phenylene ethynylene systems as foundation architectures for molecular wires. Chapter 2 describes the synthesis of oligo-phenylene ethynylene pro-ligands of the general form Me3SiC=CC6H4C=CC6H4R (1-5), in which R is either an electron donor (Me, OMe) or acceptor (CC^Me, NO2, CN). Chapter 3 discusses the synthesis of the gold(I) oligo-phenylene ethynylene complexes. Chapter 4 examines the synthesis of half-sandwich Ru(L2)Cp' [L = PPh3, Cp' = Cp ; L2 = dppe, Cp' = Cp*) acetylide complexes derived from simple phenyl, tolan and oligo(phenylene ethynylene) based acetylenes. Chapter 5 describes the synthesis of some cluster complexes. Chapter 6 explores the novel, preparative scale stoichiometric transmetallation reactions involving the simple Au(C=CR)(PPh3) (R = Ph or CelTjMe) complexes. Chapter 7 concludes the general summary of the thesis and discusses briefly the findings achieved in each chapter.en_US
dc.language.isoenen_US
dc.publisherDurham Universityen_US
dc.subjectQD 410 .W3 2007en_US
dc.subjectWan Mohd Khairul Wan Mohamed Zinen_US
dc.subjectOrganometallic complexes featuring oligo-phenylene ethynlene ligandsen_US
dc.subjectOrganometallic compoundsen_US
dc.titleOrganometallic complexes featuring oligo-phenylene ethynlene ligandsen_US
dc.typeThesisen_US
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